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No-Poo or Shampoo free is cleansing your hair without use of harsh chemicals or store bought compounds.
Basics
Why go shampoo free?
What's so bad about shampoo anyway?
How do I do it?
How does this whole thing work?
What kind of herbs can I use to improve my hair's health?
Can I use hairspray/products and colour my hair?
Troubleshooting
My hair is too long!
My hair has feels greasy!
My hair feels dry!
I have white buildup!
My head is itchy!
I have dandruff!
I have limp or weak hair!
I have hard water!
Why go Shampoo Free?
      Going shampoo free is easier on your hair's health, your wallet, and your time. For $5.00 you can purchase enough baking soda and apple cider vinegar to take care of your hair for months, whereas the same can barely buy you one bottle of commercial shampoo! When done correctly, your hair won't smell or feel oily (or dry) and be healthier and happier then when you were using shampoo. It will be easier to manage and stay clean for much longer (some people don't experience greasiness ever again once they've returned their hair to it's natural state). Anyone with small children who hasn't used baby shampoo will be aware of how, even after days and days of toddler mayhem, even after playing and sweating, thier hair does not get greasy. I know I'm always amazed that even after waking up sweaty my daughter's hair can be soft, silky and smell nice.
      Your hair is a very important part of your body that's often overlooked. On top of accentuating your style and appearance, your hair can give you clues to your health. Greasy, limp hair can be a sign of bad diet, while brittle and dry hair can be a sign of malnutrition and undernourishment. If you're anemic, deficient in calcium or other vitamins, your hair and fingernails will give you some of the first clues. Taking proper care of your hair and returning it to it's natural state may be one of the best things you can do for your appearance.
What's so bad about shampoo anyway?
      Shampoo is a detergent, just like laundry detergent, dishwashing powder and the stuff you use to clean your bathroom. It cleans out the dirt in your hair, but is very harsh and also takes the natural oils that make your hair shiny, soft and strong. Shampoo wasn't introduced until the early 20th century, before that many people used soap. Soap can wash your hair without removing as much of the natural oils that shampoo does. Unfortunately, it doesn't stand very well in alkaline water. When mineral levels in water began to rise, that made soap a messy, poor item to wash with. It causes 'soap scum' rings around your tub and on your shower doors. Alkali (hard water) makes the scales on your hair stand up, feel rough and get tangled. When washing with water with a higher alkaline content and soap, the "soap scum" gets all tangled up in your hair, is much harder to wash out, and creates a big mess. Shampoo came out on the market just in time, displaying it's only real benefit: it behaves similarly both in hard and soft water. Therefore it was a "superior" product to an old favorite, soap. But it didn't come without problems. Because shampoo is harsh enough to strip the natural oils from your hair, you need something to replenish them. Conditioner was born. You need to wash your hair every day not because it gets dirty, but because the oils from the conditioner don't last and need to be replenished.
      The oils in your hair come naturally out of your scalp to nourish it. Stripping them away causes damage, and breakage over time. In a way you do need conditioner, if you use shampoo - because it covers up the damage that's been done. But you don't need shampoo in the first place, all you're spending your money on is a big bottle of perfumed detergent.
      Most shampoos contain mineral oil. A byproduct of the distillation of gasoline from crude oil, mineral oil is what's left over. It's so abundant that it costs more to dispose of it then it does to package and sell it, so it ends up everywhere. It's added to shampoos and conditioners to give hair an artificial shine caused by coating it with a thick oil. Mineral oil cannot absorb into your skin like other oils do, so it sits on top and forms a barrier preventing oils and toxins from being released as a normal part of your skin's lifecycle. This is one of the reasons you'll find that the more shampoo you use, the more often you need to use it. In the long run, coating your hair with mineral oil makes it weaker, and more prone to damage.
      If mineral oil doesn't scare you, maybe the other ingredients will. SLS and SLFS (sodium lauryl sulfate, sodium laureth sulfate) are skin and eye irritants that also acts as a foaming agent in soaps, shampoos, toothpastes, dishwashing liquid... and just about anything that produces a foamy lather. The Materials Safety Data Sheet cautions to avoid body contact with SLS, it also puts infants and children (whose eye are developing at a more rapid rate) at risk for improper eye development when it's absorbed through the skin and accumulates in eye tissues.
      Because of residual levels in internal organs, it's questioned how safe our current rates of exposure are. "Debunkers", and companies who sell products containing these ingredients claim that the short exposure (shampoo and rinse) isn't enough for it to build up, and that by itself, in the dilution present within the product, the ingredient won't cause damage. This is basically true, however neither take into account recent reports (within the last five years), exposure due to the amount of products which contain SLS/SLFS and how often we use them, and the known chemical reaction with other ingredients commonly found in these products.
      While not carcinogens, both these substances, when mixed with other ingredients commonly found in shampoo bottles, may cause carcinogenic nitrates to form. Using it in moderation, and even in high amounts probably isn't going to kill you - but it's certainly not improving your health. The suggested safe percentage of SLS or SLFS to be used in products like shampoo and toothpaste isn't adhered to as often as it should be.
      In its final report on the safety of sodium lauryl sulfate, the Journal of the American College of Toxicology notes that this ingredient has a "degenerative effect on the cell membranes because of its protein denaturing properties." What's more, the journal adds, "high levels of skin penetration may occur at even low use concentration."
      Interestingly, sodium lauryl sulfate "is used around the world in clinical studies as a skin irritant," notes the journal. The publication expressed additional concerns:
    Carcinogenic nitrosamines can form in the manufacturing of sodium lauryl sulfate or by its inter-reaction with other nitrogen-bearing ingredients within a formulation utilizing this ingredient.
    Other studies have indicated that sodium lauryl sulfate enters and maintains residual levels in the heart, liver, lungs and brain from skin contact. This poses the question whether it could be a serious potential health threat from its use in shampoos, cleansers, and toothpastes.
    Still other research has indicated sodium lauryl sulfate may be damaging to the immune system, especially within the skin. Skin layers may separate and inflame due to its protein denaturing properties.
    Although sodium lauryl sulfate is not carcinogenic in experimental studies, it has been shown that it causes severe epidermal changes in the area it is applied, indicating a need for tumor-enhancing assays.
    Additional studies have found that sodium lauryl sulfate is heavily deposited on the skin surface and in the hair follicles. Damage to the hair follicle could result from such deposition.
Links:
Material Safety Data Sheet [mineral oil]
SLS and SLES
Sodium Laureth Sulfate, 'Chemical Cocktail'
Snopes.com piece on rumors that SLS causes cancer.
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How do I go shampoo free?
      Use one tablespoon per one cup of warm or hot water. You can double or triple the recipe if you have very, very long or thick hair. But do not use more baking soda, your hair will become hard, dry or feel brittle if you use too much. You can put this mix in a recycled shampoo bottle, and apply to your hair with warm water.
      The mix should not feel gritty, and should be a liquid. If you have very short or thick hair, you may find it easier to make a paste with a tablespoon of baking soda (or less) and sprinkle it over very wet hair and massage in. Otherwise, spray or pour the mixture onto your hair and work it in. Let it sit about a minute, and then rinse. I personally find it easiest to make a liquidy paste in the palm of my hand with about half a tablespoon, and then sprinkle and massage into dripping wet hair. I have very short hair, so I use less. Experiment and see what works best for you, there are no official rules.
      For a typical rinse, make up a solution of one to two tablespoons of Apple Cider Vinegar (ACV) per cup of water. Apply to wet hair, massage into scalp and rinse off with cold water.
What do these ingredients do?
      Apple cider vinegar is a mild acidic made from fermenting apples, the acid content is usually only around 3-5% in store-bought ACV. It has a lot of health benefits when taken internally, too! When used on your scalp, it helps promote circulation, acts as a natural antiseptic, and dissolves excessive fatty deposits and reduces scaling or peeling of the skin. As for use on hair, it helps to clarify, detangle, balances hair's pH level and seals the cuticles. Some people are bothered by the smell, but be assured that the smell should dissipate within a moment or two of rinsing. If it doesn't, you're using too much in your solution!
      Baking soda is the weakest alkali of sodium compounds, it would take using a lot to do damage to your skin or hair. It has a lot of useful properties like deodorizing, leavening (for baking), whitening, polishing and clarifying. You only need a little bit, regardless of what you're using it for. Just like with vinegar, a little goes a long way. Plain water can remove almost all the dirt you can get in your hair, but a little baking soda can not only remove the rest, but take care of the build-up from hair products, shampoos and anything else you might pick up. Some people find that over time, using baking soda in their hair will lighten the colour - although most agree that if this happens you're using it too much, and perhaps not using enough ACV. Once or twice a week is fine, even less if your hair is in very good condition or easy to manage.
      Use warm water to wash or clarify, this opens up your hair cuticles and helps your conditioner or rinse penetrate the hair. Use cool water on low pressure to rinse to close the cuticle, cut down on frizzes, soften hair and enhance curls.